WebNon Equilibrium Modeling of Sorption of Gases and Vapors in Polymers of Intrinsic Microporosity (PIM) 2012 / M. Minelli, K. Friess, O. Vopicka, V. Hynek, M. Lanc, et al. Energy-efficient polymeric gas separation membranes for a sustainable future: A review WebA polymer of intrinsic microporosity (PIM-1) containing nitrile groups was reacted by [2 + 3] cycloaddition reaction to give a polymer substituted with tetrazole groups (TZ-PIM), and then was further methylated to give a new PIM substituted with methyl tetrazole groups (MTZ-PIM). In contrast to TZ-PIMs, the MTZ-PIMs had distinctly improved solubility …
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WebThe gas permeation parameters (permeability (P), diffusion (D) and solubility (S) coefficients) were determined for these polymers. These PIM-PIs exhibit both high apparent surface areas and high gas permeability coefficients, greater than those of most polyimides studied so far and only slightly smaller than the permeability coefficients of the archetypal … WebFeb 1, 2024 · “Polymers of Intrinsic Microporosity,” which is . introduced and abbreviated as “PIMs,” is a new category of a membrane-forming polymer and relative ly a . how much snow at china peak
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WebApr 13, 2024 · Among the vast number of examples, polymer of intrinsic microporosity-1 (PIM-1) is a prominent, ladder-type, soluble, and permanently porous polymer 6 with a … WebJan 17, 2024 · In this study, a facile, controllable, and versatile chemical vapor amination strategy is reported to simultaneously tune gas sorption and diffusion in polymer of … WebThe resulting polymer was structurally characterized and proven permanently porous with a surface area of 305 m2 g−1. The high concentration of amines (–NH– and –NH2) within the backbone of the polymer result in exceptional selectivity (141) for CO2 over N2 and dynamic capacity (15.1 cm3 g−1) in the presence of water (20 : 80 v/v CO2 : N2, 91% relative … how do thickeners work